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Được đăng ngày 18 Tháng 5 2012 Xem: 0
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Open, Ring! Highly electrophilic cationic complexes as catalysts in immortal ring-opening polymerization of lactide

(Phys.org) -- Certain complexes of large alkaline earth elements such as calcium, strontium, and barium are efficient catalysts for various organic reactions. However, the stability of these heteroleptic complexes in solution is compromised by ligand scrambling. The β-diketiminato ligand has proven especially useful in stabilizing reactive heteroleptic complexes of calcium, but to a lesser extent those of larger alkaline earth elements.

French researchers now report well-defined (β-diketiminato)calcium and -strontium cationic complexes paired with weakly coordinating anions that are extremely active in the immortal ring-opening polymerization of lactide, with a good degree of control of polymerization parameters, and display unusual reactivity by providing a unique example of oxidation of

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Viết bởi news.h2vn.com Chuyên mục: Chemistry News
Được đăng ngày 18 Tháng 5 2012 Xem: 1
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A new method detects traces of veterinary drugs in baby food

The amount of veterinary drugs detected in baby food is very low and not worrying, but it shows a need for control. Credit: SINC

The quantities are very small, but in milk powder and in meat-based baby food, residues of drugs given to livestock were found. Researchers from the University of Almería (Spain) have developed a system to analyse these substances quickly and precisely.

Antibiotics, such as tilmicosine, or antiparasitic drugs, such as levamisole, are given to livestock in order to avoid illness, but they can remain later in food. Scientists from the University of Almeria (UAL) have confirmed this, whilst checking new methodology to identify the minute quantities of these substances that remain in baby food preparations.

"The concentrations detected have been generally very low. On

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Viết bởi news.h2vn.com Chuyên mục: Chemistry News
Được đăng ngày 18 Tháng 5 2012 Xem: 1
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Chemists merge experimentation with theory in understanding of water molecule

The water hexamer, shown, is the smallest assembly of water molecules that adopts a three-dimensional structure displaying hydrogen bonding patterns characteristic of liquid water and ice.

(Phys.org) -- Water is the most abundant and one of the most frequently studied substances on Earth, yet its geometry at the molecular level – the simple two hydrogen atoms and one oxygen atom, and how they interact with other molecules, including other water – has remained somewhat of a mystery to chemists.

Most understanding at that level is theoretical, requiring the use of supercomputers to make innumerable calculations over periods of weeks to make educated guesses as to the arrangements and structure of water clusters before they form into liquid water or ice.

But a new study, using experimentation

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Rare-earth half-sandwiches prove rewarding

Figure 1: Modification of nitrogen-bearing pyridine compounds (far left) with olefins (blue spheres, left) at an ortho-C-H position (yellow sphere) can be performed selectively and efficiently, using novel rare-earth catalyst complexes. Credit: 2012 Zhaomin Hou

The chemical frameworks of ’natural products’—molecules generated by biological organisms—have inspired many of today’s most potent pharmaceuticals. But the complexity of these compounds makes time-consuming tricks necessary to produce them at large scales. Bing-Tao Guan and Zhaomin Hou from the RIKEN Advanced Science Institute in Wako, however, have developed a rare-earth catalyst system that promises to make natural product synthesis significantly easier by enabling direct modification of aromatic pyridine compounds.

Pyridine, a

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Viết bởi news.h2vn.com Chuyên mục: Chemistry News
Được đăng ngày 18 Tháng 5 2012 Xem: 0
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Daejeon, the Republic of Korea—In our everyday life, we use gasoline, diesel, plastics, rubbers, and numerous chemicals that are derived from fossil oil through petrochemical refinery processes. Fossil resources are limited and not sustainable. Our world is facing problems associated with climate change and other environmental problems resulted from lavish consumption of fossil fuels. One solution to address these problems is to use renewable, non-food biomass for the production of chemicals, fuels, and materials through biorefineries.

In their paper published online in Nature Chemical Biology on May 17th, Professor Sang Yup Lee and his colleagues at the Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST), newly present general

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